Tests carried out in a vacuum apparatus with a quartz microbalance in the spring . Reading accuracy is 4 × 10 - sample surface g / cm . Titanium Welded Tubes Mercury manometer measuring system connected to the reaction chamber using the pressure.
Titanium iodide as a sample . Breaking titanium strip cold rolled to a rod 0.7 mm thick . Then cut the strip size is 9 × 25 mm sample . In order to eventually remove surface dirt , before the test sample with a finely sandpaper and etched in 7% HNO3 solution in HF.
The tube is filled with distilled water and vacuum means connected to the plug and the device as a source of water vapor . In order to remove the dissolved water gasification will remain for some time in the water under the stars . Samples were heated to a predetermined temperature in a vacuum after the tube with water and the system is turned on, and set up the equilibrium vapor pressure corresponds to the temperature in the system . When the system is full , the system is filled with water and cut off the tube , Titanium heat exchangers and then tested in a closed volume.
Under 800,850,900 and 950 ℃ and 14 mm Hg vapor pressure tested titanium plate and steam reaction.
Kinetics of these tests indicate that , in the beginning stage of the reaction , the reaction with water vapor titanium plates subject to the parabolic law . After the reaction started after a certain period of time becomes linear parabolic law rule.
In order to identify the effect of pressure on the reaction rate , once at 4 mm Hg pressure two experiments.
Titanium plate during the reaction and steam , and any of metals, and also the reaction gas , is composed by a number of successive stages , in which the main are: 1 ) the gas molecules collide with the metal , 2 ) gas molecules adsorbed on the metal surface 3 ) the dissociation of the gas molecules , 4 ) through the surface of the film agent diffusion reaction product , 5 ) chemical reaction.
The reaction rate depends on the speed of the pro stage . It was found that the reaction pressure is reduced because the rate of 5 /6 and steam manganese Titanium heat exchangers remains unchanged , so it should be acknowledged that the reaction speed depends on the diffusion of the reagents through the surface of the membrane , since it is the only one speed stage and the gas pressure independent.
Titanium pump is manufactured in the selection of equipment, the use of titanium and titanium alloy has corrosion resistance, the proportion of small, high strength, high temperature and good mechanical properties, the flow components, impeller and seals and other packing integrated titanium nodes or titanium alloy.
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